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Analysis of 5-chloro-8-methoxy-2-(bromomethyl)quinoline by XPS
Thomson, Jeff Stoker, Josh Bunker, Jared Agbonkonkon, Nosa Iyer, Gayathri Bronson, R. Todd Savage, Paul B. Linford, Matthew R. Husseini, Ghaleb
Thomson, Jeff
Stoker, Josh
Bunker, Jared
Agbonkonkon, Nosa
Iyer, Gayathri
Bronson, R. Todd
Savage, Paul B.
Linford, Matthew R.
Husseini, Ghaleb
Date
2004
Advisor
Type
Peer-Reviewed
Article
Published version
Article
Published version
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Abstract
Macrocyclic ethers are used extensively for their ability to form strong and selective interactions with charged species. It has been shown that the incorporation of heterocyclic groups into macrocylclic ethers increase rigidity and interaction with certain ions. Alkylation of these azacrowns with benzylic halides can attach fluorionophoric substituents onto the ring. One of the molecules used for this alkylation is 5-chloro-8-methoxy-2-(bromomethyl)quinoline. Azacrowns with this alkyl ligand have displayed interesting ion complexation properties.