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    Characterization of PM₂̣ ₅ at a Traffic Site Using Several Integrated Analytical Techniques
    (Wiley, 2020) Hamdan, Nasser; Alawadhi, Hussain; Shameer, Mohamed
    We have conducted a comprehensive, year-long, sampling campaign for particulate matter (PM) at a site near a major highway, following standard protocols. Total mass, elemental and chemical composition of the fine fractions (PM₂ ̣₅) of particulates originating from traffic are determined using several complementary techniques. These complementary techniques include gravimetric analysis, X-ray fluorescence, scanning electron microscopy and energy dispersive spectroscopy, X-ray diffraction (XRD) and black carbon multiwavelength absorption. Conducting an enrichment factor analysis and correlation coefficient calculations on elements show that Si, Ca, Al, Fe, Ti, Mn, Mg, K, Na and Cr are of crustal origin, while P, Cl and V are enriched slightly from human activities. All other measured elements (Rb, Zr, Ba, Sr, S, Ni, Cu, Zn and Pb) have high enrichment factors and relate to anthropogenic sources. Sulfates in the form of mascagnite and koktaite had the largest contribution to PM₂ ̣₅ (43% of total PM concentration). Natural pollutants such as quartz, calcite, iron oxide and aluminum oxide originating from the crust also contribute to PM₂ ̣₅ eBC and elements such as Zn, Ba, Cu, Fe and S are related to traffic emissions such as exhaust emissions and tire, brakes and road erosion. Correlation coefficients and enrichment factor calculations helped identify elements that are related to natural emissions and those related to anthropogenic sources. Being an arid region, the PM₂ ̣₅ mass concentrations were found to be within or slightly above international air quality standards.
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    Source apportionment of PM₂̣ ₅ and PM₁₀ pollutants near an urban roadside site using positive matrix factorization
    (Elsevier, 2024-07) Anwar, Shahid; Shameer, Mohamed; Alawadhi, Hussain; Hamdan, Nasser
    This paper presents results from a comprehensive study of source apportionment of particulate matter (PM) of size PM₂̣ ₅ and PM₁₀ near a busy highway in Sharjah, United Arab Emirates. Source apportionment was carried out using US Environmental Protection Agency (EPA) Positive Matrix Factorization model. Furthermore, backward trajectory analysis and Potential Source Contribution Function were used to assess air mass transport pathways and identify potential source regions, respectively. The results revealed six major sources for PM₂̣ ₅, including traffic, sea salt, fugitive dust, secondary aerosols, heavy oil combustion and mineral dust. For PM₁₀, four major sources were identified, including secondary aerosols, traffic, sea salt and mineral dust. Traffic emissions were found to be significant contributors to both PM₂̣ ₅ and PM₁₀ pollution, along with natural sources like sea salt and mineral dust. Backward trajectory analysis indicated the influence of different wind regimes on air mass transport, with contributions from regions like Arabian Gulf, Arabian Sea, Oman and Iran. The Conditional Bivariate Probability Function analysis further explained the impact of local traffic emissions and other sources on PM pollution under varying wind conditions.
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    In-situ grown ternary metal hydroxides@3D oriented crumpled V₂C MXene sheets for improved electrocatalytic oxygen evolution reaction
    (Elsevier, 2024-08) Iqbal, Anum; Sabouni, Hamzeh; Hamdan, Nasser
    High valence multi transition metal hydroxides are greatly enriched with OER redox active sites due to strong synergy of heteroatomic nuclei. The efficiency of these redox active sites could be efficiently improved by coupling with highly conductive substrate. The advanced three-dimensional (3D) architecture and hydrophilic terminal functionalities of MXene (MX) considerably enhance the maximum utilization rate of anchored redox active sites by triggering the direct growth of these at MX substrate. Here-in, the freeze-dried 3D network of crumpled Vanadium-Carbide (V₂C) MX sheets regulates the crystallization of in-situ grown NiFeCr multi transition metal hydroxides on MX scaffold through co-precipitation process. The XPS results suggest a synergistic chemical interaction of 3D MX scaffold with NiFeCr that modifies the electronic structure of the composite ensuring reduced charge transfer resistance. Besides, as found in FESEM morphological investigation, the well-dispersed NiFeCr multi-transition metal hydroxides are immobilized on open pores like structure of V₂C-MX facilitate thoroughly accessible active sites. As a result, the NiFeCr@3D V₂C-MX composite has shown an excellent electrocatalytic activity with an overpotential of 410 mV at a current density of 200 mA cm⁻², Tafel slope of 100 mV dec in 1M KOH. Besides, the significant interaction between metallic centers and MXene support prevent detachment or agglomeration of active centers providing maximum interaction with the electrolytic ions, quick ionic OH⁻ transportation, speedy and stable electron transfer channels thus ensure the long-term stability of NV-5MX during 53 h continuous operation of OER. Furthermore, we have utilized a more accurate value of half-cell standard reduction potential of the Hg/HgO electrode in the Nernst equation to represent all test voltages and to determine the overpotential values. In essence, this study features a facile approach for the confined growth of multi transition metal hydroxides in the presence of morphologically unique 3D crumpled V₂C MXene architectures. Consequently, the increased OER reaction kinetics and improved stability of the synthesized composites are potentially due to synergistic interplay between well dispersed active sites and the conductive substrate.
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    Characterization of Fine Particulate Matter in Sharjah, United Arab Emirates Using Complementary Experimental Techniques
    (MDPI, 2018) Hamdan, Nasser; Alawadhi, Hussain; Jisrawi, Najeh; Shameer, Mohamed
    Airborne particulate matter (PM) pollutants were sampled from an urban background site in Sharjah, United Arab Emirates. The fine fraction (PM₂̣ ₅) (particulates with aerodynamic diameters of less than 2.5 μm) was collected on 47-mm Teflon filters and analyzed using a combined set of non-destructive techniques in order to provide better understanding of the sources of pollutants and their interaction during transport in the atmosphere. These techniques included gravimetric analysis, equivalent black carbon (EBC), X-ray fluorescence, scanning electron microscopy, and X-ray diffraction. Generally, the PM₂̣ ₅ concentrations are within the limits set by the World Health Organization (WHO) and the United States (US) Environmental Protection Agency. The EBC content is in the range of 10–12% of the total PM concentration (2–4 µg m⁻ᵌ), while S (as ammonium sulfate), Ca (as calcite, gypsum, and calcium carbonate), Si (as quartz), Fe, and Al were the major sources of PM pollution. EBC, ammonium sulfate, Zn, V, and Mn originate from anthropogenic sources such as fossil fuel burning, traffic, and industrial emissions. Natural elements such as Ca, Fe, Al, Si, and Ti are due to natural sources such as crustal materials (enhanced during dust episodes) and sea salts. The average contribution of natural sources in the total PM ₂̣ ₅ mass concentration over the sampling period is about 40%, and the contribution of the secondary inorganic compounds is about 27% (mainly ammonium sulfate in our case). The remaining 22% is assumed to be secondary organic compounds.
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    (2024) Glasgow, Fiona

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