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Design of systems for hydrogen production based on the Cu-Cl thermochemical water decomposition cycle: Configurations and performance

Orhan, Mehmet Fatih
Dincer, Ibrahim
Rosen, Marc A.
Date
2011-08
Advisor
Type
Article
Degree
Description
Abstract
In this study, we analyze several Cu-Cl cycles by examining various design schemes for an overall system and its components, in order to identify potential performance improvements. The factors that determine the number and effective grouping of steps for new design schemes are analyzed. A thermodynamic analysis and several parametric studies are presented for various configurations. The energy efficiency is found to be 44% for the five-step thermochemical process, 43% for the four-step process and 41% for the three-step process, based on the lower heating value of hydrogen. Also, conclusions regarding implementation of these new configurations are discussed and the potential benefits ascertained.